She won the title Binibining Pilipinas International through Binibining Pilipinas 2012 pageant where she was also titled as Best in Swimsuit and Best in National Costume from that edition. In the question-and-answer portion, Schmitz, a law student, was asked by one of the judges John Martin Miller, "Which you would rather be, someone who's respected or someone who is loved and why?" Her answer: "I would rather be someone respected because that means you maintain your integrity, dignity and self-respect and that means that in turn you will be loved by whoever matters and everyone around you." At that time, 'Nicole Schmitz' trended on Twitter both Worldwide and Philippines. After winning, she got a courtesy call from the mayor of her hometown Cebu City specifically in Liloan. She received a token of appreciation. She also had a homecoming on her mother's hometown Jimenez, Misamis Occidental, Mindanao. This is where she was also invited as a judge for the Search for BB. Jimenez 2012. She also answered in a different event the question of why "It's More fun in the Philippines": "To be honest, I've just never been anywhere else in the world where the people are so friendly, warm, and able to just have a laugh and joke about themselves. That's truly a unique experience in the Philippines, I think." She adds that the Filipinos find joy in the simplest things and this is one more reason why it is more fun in the Philippines. She also entered Top 13 in Binibining Pilipinas 2007. In the question-and-answer portion, she was asked by one of the judges Miss Universe 1994 Philippines' representative Charlene Gonzales: "What is your biggest fear and what have you done to overcome it?" Her response: "My greatest fear is actually having regret. In anyone's life, it doesn't benefit them if they're gonna regret something so what I do to combat that is that I just make sure that everything I do it's because I want to do it. I don't do something with any doubts in my mind. I do it with sureness and I'm very confident in myself and in that way, that's how I combat that. Thank you." She entered the top 15 on Miss International 2012 continuing the streak of the Philippines now for five years. She had her final speech as:
“Peace, love, unity, these 3 words are the Miss International pageant. Having spent the past 3 weeks in Okinawa, I have witnessed the special connection it has with the world. Globalization and multi cultural diversity can exist. We can be uniquely global and globally unique. This is my mission. I want people to appreciate that we not only belong to local communities but world at large. By this understanding we can contribute to global goals. I am standing here in front of you open to offer my heritage and myself, as a strong compassionate responsible and independent woman in this quest for global harmony. And I can stand here proudly and consider myself an international citizen.”
She has been doing modelling internationally on the side for 7 years now. She described herself as a "pretty laid-back and easy-going, although she is not into nudity or sleazy pictures. Sophisticated sexy and edgy attitude is what she's into. She believes with this mixture gives me unique look, something that can be played upon and developed in pictures." Nicole is currently studying Law/Psychology at Macquarie University in Sydney, Australia and is expected to graduate with honors.