UN numbers are four-digit numbers that identify hazardous materials, and articles in the framework of international transport. Some hazardous substances have their own UN numbers, while sometimes groups of chemicals or products with similar properties receive a common UN number. A chemical in its solid state may receive a different UN number than the liquid phase if their hazardous properties differ significantly; substances with different levels of purity may also receive different UN numbers. UN numbers range from UN 0004 to about UN 3548 and are assigned by the United NationsCommittee of Experts on the Transport of Dangerous Goods. They are published as part of their Recommendations on the Transport of Dangerous Goods, also known as the Orange Book. These recommendations are adopted by the regulatory organization responsible for the different modes of transport. There is no UN number allocated to non-hazardous substances. For more details, see Lists of UN numbers. NA numbers, are issued by the United States Department of Transportation and are identical to UN numbers, except that some substances without a UN number may have an NA number. These additional NA numbers use the range NA 9000 - NA 9279. There are some exceptions, for example NA 2212 is all asbestos with UN 2212 limited to Asbestos, amphibole amosite, tremolite, actinolite, anthophyllite, or crocidolite. Another exception, NA 3334, is self-defense spray, non-pressurized while UN 3334 is aviation regulated liquid, not otherwise specified. For the complete list, see NA/UN exceptions. For more details see List of NA numbers. ID numbers are a third type of identification number used for hazardous substances being offered for Air transport. Substances with an ID number are associated with proper shipping names recognized by the ICAO Technical Instructions. ID 8000, Consumer commodity does not have a UN or NA number, and is classed as a Class 9hazardous material.
Hazard identifiers
Associated with each UN number is a hazard identifier, which encodes the general hazard class and subdivision. If a substance poses several dangers, then subsidiary risk identifiers may be specified. It is not possible to deduce the hazard class of a substance from its UN number: they have to be looked up in a table.
