Released as a single and as a 12" remix, it went to No. 1 on the Billboard Dance/Disco chart as well as the Canadian Singles Chart. It was their biggest hit in the UK Singles Chart, peaking at No. 4. On the AmericanCash Box Top 100, it got as high as No. 9, and on the BillboardHot 100 it peaked at No. 18. The single consists of four parts, referred to as "Parts One, Two, Three and Four". Part One is the standard album version, Part Two is an instrumental version, Part Three is a vocal version without the orchestral overdubs and Part Four is a short acoustic instrumental part of the song, containing strings and horns, as well as occasional harp plucks and xylophone. A different US remix dub version by producer Trevor Horn appeared as A-side on the 1982 US 12". The '82 US remix dub version was not widely available after its initial release, but the track remained much in demand by club DJs and fans alike and copies of the original 12" version fetched high prices. When Neutron discovered this, they issued a limited edition DJ-pressing of the Horn remix in November 1982 as a DJ promo 12" vinyl under the title "ABC Look of Love Special Remix 12" Neutron NTXDJ103. Through the 1980s, BBC Radio 1 DJ Gary Davies used the last crescendo on Part 4 of the song as a closing theme to his daily lunchtime programme called The Bit in the Middle, only changing it in 1991 when his show was rebranded as Let's Do Lunch and given fresh music beds and themes. The US B-side, entitled "Theme from Mantrap", was an alternate version of "Poison Arrow". In February 2014, all four parts appeared together as one single track on the ZTT compilation "The Art of the 12" Volume Three". The lyrics of the song, as well as others on The Lexicon of Love, were inspired by a break-up lead singerMartin Fry had experienced. In the second verse, during the phrase "When your girl has left you out on the pavement", the "Goodbye" background vocal is spoken by the actual woman in the relationship who had jilted him.
Music video
The music video for the song, taped on a soundstage, was influenced by old British music hall, the chalk pavement sequence in the film Mary Poppins, carnival sideshows, and Punch and Judypuppet shows; the four band members were featured wearing Edwardian-style light suits with vertical pastel stripes, accompanied by many colourful extras, including a Charlie Chaplin impersonator and cameos from producer Trevor Horn and music promoter and journalist Paul Morley. The video vaguely pays homage to the ballet sequence from An American in Paris.
In 1990, to promote the compilation album Absolutely, a new remix of the song by Paul Staveley O'Duffy was officially released, though without participation or approval from the band's members. The remix incorporates part of the melody from Kraftwerk's "Computer Love", which had been in the UK Top 40 at the same time as the original release of "The Look of Love" in 1982.