In 1996 contribution to quantum electrodynamics, Iwo Bialynicki-Birula used the Riemann–Silberstein vector as the basis for an approach to the photon, noting that it is a "complex vector-function of space coordinates r and time t that adequately describes the quantum state of a single photon". To put the Riemann–Silberstein vector in contemporary parlance, a transition is made: Bialynicki-Birula acknowledges that the photon wave function is a controversial concept and that it cannot have all the properties of Schrödingerwave functions of non-relativistic wave mechanics. Yet defense is mounted on the basis of practicality: it is useful for describing quantum states of excitation of a free field, electromagnetic fields acting on a medium, vacuum excitation of virtual positron-electron pairs, and presenting the photon among quantum particles that do have wave functions.
Multiplying the two time dependent Maxwell equations by the Schrödinger equation for photon in the vacuum is given by where is the vector built from the spin of the length 1 matrices generating full infinitesimal rotations of 3-spinor particle. One may therefore notice that the Hamiltonian in the Schrödinger equation of the photon is the projection of its spin 1 onto its momentum since the normal momentum operator appears there from combining parts of rotations. In contrast to the electron wave function the modulus square of the wave function of the photon is not dimensionless and must be multiplied by the "local photon wavelength" with the proper power to give dimensionless expression to normalize i.e. it is normalized in the exotic way with the integral kernel The two residual Maxwell equations are only constraints i.e. and they are automatically fulfilled all time if only fulfilled at the initial time , i.e. where is any complex vector field with the non-vanishing rotation, or it is a vector potential for the Riemann–Silberstein vector. While having the wave function of the photon one can estimate the uncertainty relations for the photon. It shows up that photons are "more quantum" than the electron while their uncertainties of position and the momentum are higher. The natural candidates to estimate the uncertainty are the natural momentum like simply the projection or from Einstein formula for the photoelectric effect and the simplest theory of quanta and the, the uncertainty of the position length vector. We will use the general relation for the uncertainty for the operators We want the uncertainty relation for i.e. for the operators The first step is to find the auxiliary operator such that this relation can be used directly. First we make the same trick for that Dirac made to calculate the square root of the Klein-Gordon operator to get the : where are matrices from the Dirac equation: Therefore, we have Because the spin matrices 1 are only to calculate the commutator in the same space we approximate the spin matrices by angular momentum matrices of the particle with the length while dropping the multiplying since the resulting Maxwell equations in 4 dimensions would look too artificial to the original : We can now readily calculate the commutator while calculating commutators of matrixes and scaled and noticing that the symmetric Gaussian state is annihilating in average the terms containing mixed variable like Calculating 9 commutators and estimating terms from the norm of the resulting matrix containing four factors giving square of the most natural norm of this matrix as and using the norm inequality for the estimate we obtain or which is much more than for the mass particle in 3 dimensions that is and therefore photons turn out to be particles times or almost 3 times "more quantum" than particles with the mass like electrons.