In 1794, he joined the Hesse-Darmstadtbrigade, which was stationed in the Netherlands. He held the rank of captain and was taken prisoner by the French. He was released ten months later, after his relatives had bought his freedom. In 1796, he joined the Austrian army. He took part in the campaigns of 1798, 1799 and 1800. After the Treaty of Lunéville, he was stationed in Lviv. In 1805, he was promoted, first to Lieutenant colonel, then to colonel and was appointed commander of the Infantry Regiment No. 2 Archduke Ferdinand. He fought under Archduke Charles in the Battle of Caldiero in 1805 and in the battles of Battle of Landshut and Eckmühl. After the Battle of Aspern-Essling, he was promoted to Major General on the battlefield, for his outstanding performance. He was injured during the Battle of Wagram and subsequently received the Military Order of Maria Theresa. He was transferred to Vienna and his brigade was part of an army corps led by Karl Philipp, Prince of Schwarzenberg. In 1813, he was promoted to Feldmarschallleutnant and fought in the battles of Dresden, Kulm and Lindenau. He briefly served as governor of the Grand Duchy of Frankfurt and the Principality of Isenburg. In February 1814, he assumed command of the 6th German army corps and marched into Lyon on 22 March. In 1818 and 1820, he travelled to Russia and England, to carry out diplomatic missions. In 1821, during the early revolutionary of the Risorgimento, he was sent to Naples as commander of an Austrian division, and was then appointed governor of Naples. In 1825, he was transferred to Graz, in 1827 to Lviv and in 1829 back to Graz. In 1832, he was promoted to Feldzeugmeister. On 28 November 1846, shortly before his death, to field marshal. This was the highest rank ever achieved by members of the House of Hesse.
Reign
In 1839, his elder brother Louis William died in Philip inherited Hesse-Homburg. In 1840, Philip was appointed as governor of Mainz; he left the government of his principality to his younger brotherGustav. The two major events of his reign were:
In December 1844, the citizens of the landgraviate demanded a constitution — this can be seen as a precursor to the revolutions of 1848. Philip considered the proposed constitution, however, he eventually rejected the proposal.
Since Philip had no children, Gustav inherited Hesse-Homburg in 1846.
Marriage
In 1838, Philip married morganatically with Rosalie Antonie, Baroness Schimmelpfennig von der Oye, née Pototschnig. Elector William II of Hesse-Kassel elevated her to Countess of Naumburg. Philip's relatives nevertheless rejected her, on the grounds that she was not a member of the high nobility. The marriage remained childless. His wife died on 21 February 1845; he survived her by nearly a year and a half. She was buried in the crypt of Bad Homburg Castle, where Philip would later be buried as well.