Metarauchite occurs as a secondary mineral in strongly oxidized polymetallic vein material. Metarauchite is found primarily in two localities, the northern part of the Jáchymov ore district, northwestern Bohemia, Czech Republic and the , Neustädtel, Germany. It's commonly associated with metazeunerite, erythrite, and gypsum and Ni-bearing , metazeunerite, pharmacosiderite. Both localities have a surface containing strongly altered aggregates of primary ore with relics of uraninite, arsenopyrite and nickelskutterudite and traces of native bismuth at the Schweitzer vein in the .
Physical properties
Metarauchite exhibits yellow to light greenish-yellow crystals, up to 0.8 mm in size, these crystals are transparent to translucent and display vitreous to pearly luster. It exhibits a hardness of 2 on the Moh's Hardness Scale. Displays thick tabular crystals, with a prevalent pinacoid. Metarauchite is very brittle and shows perfect cleavage along the plane. Metarauchite does not exhibit fluorescence either in short- and long-wavelength ultraviolet radiation. The density of metarauchite is not easily measured because of the relatively small size of most of its crystals; hence only the calculated density from the unit cell parameters and empirical formula was obtained, giving the value 3.81 g/cm3.
Optical properties
Metarachite is biaxial negative, it exhibits its 2V is calculated at 52°. Metarauchite is non-pleochroic and displays no observable dispersion and a of 0.03.
Chemical properties
Metarauchite is a Ni- and As-dominant member of the group of hydrated uranyl arsenates and phosphates with the autunite-type sheet containing divalent cations in their inter-layer. It is only isostructural with syntheticmetakirchheimerite. Metarauchite displays prominent substitution for Mg with Co, but magnesium is more commonly substituted with Ni in species found at the Schneeberg locality. The empirical formula for metarauchite is Σ0.962.01Σ1.93•8.21H2O. Simplified, the formula is Ni22•8H2O.
Metarauchite is in the triclinic crystal system, with a space group of P1 and is classed as a pinacoidal. The cell parameters are a = 7.194 Å, b = 9.759 Å, c = 13.231 Å, α = 75.53°, β = 84.01°, γ = 81.59°, which shows an a:b:c ratio of 0.737:1:1.356. The unit cell volume is 887.53 ų. Metarauchite crystals show characteristic multiply twinned along.
