Born into an upper-class family in Vorder-Brühl, near Vienna, Smoluchowski studied physics at the University of Vienna. His teachers included Franz S. Exner and Joseph Stefan. Ludwig Boltzmann held a position at Munich University during Smoluchowski's studies in Vienna, and Boltzmann returned to Vienna in 1894 when Smoluchowski was serving in the Austrian army. They apparently had no direct contact, although Smoluchowski's work follows in the tradition of Boltzmann's ideas. After several years at other universities, in 1899 Smoluchowski moved to Lwów, where he took a position at the University of Lwów. He was president of the Polish Copernicus Society of Naturalists, 1906–7. In 1913 Smoluchowski moved to Kraków to take over a chair in the Experimental Physics Department, succeeding August Witkowski, who had long envisioned Smoluchowski as his successor. When World War I began the following year, the work conditions became unusually difficult, as the spacious and modern Physics Department building, built by Witkowski a short time before, was turned into a military hospital. The possibility of working in that building had been one of the reasons Smoluchowski had decided to move to Kraków. Smoluchowski was now forced to work in the apartment of the late Professor Karol Olszewski. During his lectures in experimental physics, use of even the simplest demonstration equipment was virtually impossible. Smoluchowski lectured in experimental physics; his students included :pl:Józef Patkowski |Józef Patkowski, :pl:Stanisław Loria|Stanisław Loria and :pl:Wacław Dziewulski|Wacław Dziewulski. Smoluchowski was a member of the Copernicus Society of Natural Scientists and the Polish Academy of Sciences and Letters. His non-professional interests included skiing, mountain climbing in the Alps and the Tatra Mountains, watercolor painting, and playing the piano.
Smoluchowski died in Kraków in 1917, victim of a dysentery epidemic. Professor Władysław Natanson wrote in an obituary of Smoluchowski: "With great pleasure I recall the charm of his life, his noble cordiality, combined with exquisite kindness. I wish I could render the curious appeal of his personality, recall how temperate he was, how modest and elegantly diffident, yet always full of a pure, spontaneous joy." In 1901 he had married Zofia Baraniecka, who survived him. They had two children, Aldona Smoluchowska and Roman Smoluchowski. Roman became a notable physicist who worked in Poland, and after World War II settled in the United States.
A. Einstein and M. von Smoluchowski: "Untersuchungen über die Theorie der Brownschen Bewegung. Abhandlung über die Brownsche Bewegung und verwandte Erscheinungen", Harri Deutsch, 1997.. .
S. Chandrasekhar, M. Kac, R. Smoluchowski, "Marian Smoluchowski - his life and scientific work", ed. by R.S. Ingarden, PWN, Warszawa 1999.
E. Seneta Marian Smoluchowski, Statisticians of the Centuries pp. 299–302. New York: Springer.