List of Foreign Ministers of Spain
The following is a list of foreign ministers of Spain, since 1808 until now serving in Spain's Ministry of Foreign Affairs.
Kingdom of Spain (1808–73)
Ministers of State (1820–23/1834–73) and Secretaries of the Office of State (1808–20/1823–34)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Prime Minister | Refs |
| Pedro Cevallos Guerra | 15 October 1808 | 13 October 1809 | ||||
| Eusebio Bardají Azara | 13 October 1809 | 30 October 1809 | ||||
| Francisco Saavedra de Sangronis | 30 October 1809 | 6 February 1812 | ||||
| Eusebio Bardají Azara | 6 February 1812 | 23 June 1812 | ||||
| Carlos Martínez de Irujo y Tacón The Marquess of Casa-Irujo | 23 June 1812 | 27 September 1812 | ||||
| Pedro Gómez Labrador The Marquis of Labrador | 27 September 1812 | 11 July 1813 | ||||
| Antonio Cano Ramírez de Arellano | 11 July 1813 | 10 October 1813 | Interin | |||
| Juan O'Donojú | 10 October 1813 | 6 December 1813 | Interin | |||
| José Luyando | 6 December 1813 | 4 May 1814 | Interin | |||
| José Miguel de Carvajal y Vargas The Duke of San Carlos | 4 May 1814 | 15 November 1814 | ||||
| Pedro Cevallos Guerra | 15 November 1814 | 30 October 1816 | ||||
| José García de León y Pizarro | 30 October 1816 | 14 September 1818 | ||||
| Carlos Martínez de Irujo y Tacón The Marquis of Casa-Irujo | 14 September 1818 | 12 September 1819 | Interin | |||
| Joaquín José de Melgarejo y Saurín The Duke of San Fernando de Quiroga | 12 September 1819 | 18 March 1820 | ||||
| Evaristo Pérez de Castro | 18 March 1820 | 2 March 1821 | ||||
| Eusebio Bardají Azara | 2 March 1821 | 8 January 1822 | ||||
| Ramón López Pelegrín | 8 January 1822 | 24 January 1822 | ||||
| José Gabriel de Silva-Bazán y Waldstein The Marquis of Santa Cruz | 24 January 1822 | 30 January 1822 | ||||
| Ramón López Pelegrín | 30 January 1822 | 28 February 1822 | Interin | |||
| Francisco Martínez de la Rosa | 28 February 1822 | 5 August 1822 | ||||
| Evaristo Fernández de San Miguel | 5 August 1822 | 23 April 1823 | ||||
| José Manuel Vadillo | 25 April 1823 | 7 May 1823 | Interin | |||
| José María Pando | 13 May 1823 | 29 August 1823 | ||||
| José Luyando | 4 September 1823 | 30 September 1823 | ||||
| Victor Damián Saez | 30 September 1823 | 2 December 1823 | ||||
| Carlos Martínez de Irujo y Tacón The Marquis of Casa-Irujo | 2 December 1823 | 18 January 1824 | ||||
| Narciso Fernández de Heredia The Count of Heredia-Spínola | 18 January 1824 | 11 July 1824 | ||||
| Francisco Cea Bermudez | 11 July 1824 | 24 October 1824 | ||||
| Pedro Alcantara Álvarez de Toledo y Salm-Salm | 24 October 1825 | 19 August 1826 | ||||
| Manuel González Salmón | 19 August 1826 | 30 January 1832 | ||||
| Antonio de Saavedra y Frígola The Count of la Alcudia | 30 January 1832 | 1 October 1832 | ||||
| Francisco Cea Bermúdez | 1 October 1832 | 15 January 1833 | ||||
| Francisco de Paula Martínez de la Rosa y Berdejo | 15 January 1834 | 7 June 1835 | Moderate | Francisco de Paula Martínez de la Rosa y Berdejo | ||
| Jose María Queipo de Llano The Count of Toreno | 13 June 1835 | 14 September 1835 | Moderate | The Count of Toreno | ||
| Miguel Ricardo de Álava y Esquivel | 14 September 1835 | 4 October 1835 | Progressive | Miguel Ricardo de Álava y Esquivel | ||
| Juan Álvarez Mendizábal Acting | 4 October 1835 | 27 April 1836 | Progressive | Juan Álvarez Mendizábal | ||
| Ildefonso Díez de Rivera The Count of Almodóvar | 27 April 1836 | 15 May 1836 | Progressive | Juan Álvarez Mendizábal | ||
| Francisco Javier de Istúriz y Montero | 15 May 1836 | 14 August 1836 | Moderate | Francisco Javier de Istúriz y Montero | ||
| José María Calatrava y Peinado | 14 August 1836 | 18 August 1837 | Progressive | José María Calatrava y Peinado | ||
| Eusebio Bardají y Azara | 18 August 1837 | 16 December 1837 | Moderate | The Count of Luchana | ||
| Eusebio Bardají y Azara | 18 August 1837 | 16 December 1837 | Moderate | Eusebio Bardají y Azara | ||
| Narciso Fernández de Heredia The Count of Heredia-Spínola | 16 December 1837 | 6 September 1838 | Moderate | The Count of Heredia-Spínola | ||
| Bernardino Fernández de Velasco The Duke of Frías | 6 September 1838 | 9 December 1838 | Moderate | The Duke of Frías | ||
| Evaristo Pérez de Castro y Brito | 9 December 1838 | 19 July 1840 | Moderate | Evaristo Pérez de Castro y Brito | ||
| José del Castillo y Ayensa Acting | 19 July 1840 | 20 July 1840 | Moderate | Evaristo Pérez de Castro y Brito | ||
| Mauricio Carlos de Onís y Mercklein | 20 July 1840 | 29 August 1840 | Moderate | Antonio González y González | ||
| Mauricio Carlos de Onís y Mercklein | 20 July 1840 | 29 August 1840 | Moderate | Valentín Ferraz y Barrau | ||
| Juan Antoine y Zayas | 29 August 1840 | 11 September 1840 | Progressive | Valentín Ferraz y Barrau | ||
| Vicente Sancho y Cobertores | 11 September 1840 | 16 September 1840 | Progressive | Vicente Sancho y Cobertores | ||
| Joaquín María de Ferrer y Cafranga | 16 September 1840 | 20 May 1841 | Progressive | The Count of Luchana | ||
| Joaquín María de Ferrer y Cafranga | 16 September 1840 | 20 May 1841 | Progressive | Joaquín María de Ferrer y Cafranga | ||
| Antonio González y González Marquis of Valdeterrazo from 1864 | 20 May 1841 | 17 June 1842 | Progressive | Antonio González y González | ||
| Ildefonso Díez de Rivera The Count of Almodóvar | 17 June 1842 | 9 May 1843 | Progressive | The Marquis of Rodil | ||
| Manuel María de Aguilar y de la Puerta | 9 May 1843 | 19 May 1843 | Progressive | Joaquín María López y López | ||
| Olegario de los Cuetos y Castro Acting | 19 May 1843 | 30 July 1843 | Progressive | Álvaro Gómez Becerra | ||
| Joaquín de Frías y Moya | 10 November 1843 | 20 November 1843 | Progressive | Joaquín María López y López | ||
| Salustiano de Olózaga y Almandoz | 20 November 1843 | 29 November 1843 | Progressive | Salustiano de Olózaga y Almandoz | ||
| Luis González-Bravo y López de Arjona | 1 December 1843 | 3 May 1844 | Moderate | Salustiano de Olózaga y Almandoz | ||
| Luis González-Bravo y López de Arjona | 1 December 1843 | 3 May 1844 | Moderate | Luis González-Bravo y López de Arjona | ||
| Manuel de la Pezuela The Marquis of Viluma | 3 May 1844 | 1 July 1844 | Moderate | Ramón María Narváez y Campos | ||
| Ramón María Narváez y Campos Duke of Valencia from 1847 Acting | 1 July 1844 | 21 August 1844 | Moderate | Ramón María Narváez y Campos | ||
| Francisco de Paula Martínez de la Rosa y Berdejo | 21 August 1844 | 12 February 1846 | Moderate | Ramón María Narváez y Campos | ||
| Manuel de Pando The Marquis of Miraflores | 12 February 1846 | 16 March 1846 | Moderate | The Marquis of Miraflores | ||
| Ramón María Narváez y Campos Duke of Valencia from 1847 Acting | 16 March 1846 | 5 April 1846 | Moderate | Ramón María Narváez y Campos | ||
| Francisco Javier de Istúriz y Montero | 5 April 1846 | 28 January 1847 | Moderate | Francisco Javier de Istúriz y Montero | ||
| Carlos Martínez de Irujo The Duke of Sotomayor | 28 January 1847 | 28 March 1847 | Moderate | The Duke of Sotomayor | ||
| Joaquín Francisco Pacheco y Gutiérrez-Calderón | 28 March 1847 | 31 August 1847 | Moderate | Joaquín Francisco Pacheco y Gutiérrez-Calderón | ||
| Antonio Caballero Acting | 31 August 1847 | 12 September 1847 | Moderate | Florencio García Goyena | ||
| Modesto Cortázar y Leal de Ibarra | 12 September 1847 | 4 October 1847 | Progressive | Florencio García Goyena | ||
| Ramón María Narváez The Duke of Valencia | 4 October 1847 | 23 October 1847 | Moderate | The Duke of Valencia | ||
| Carlos Martínez de Irujo The Duke of Sotomayor | 23 October 1847 | 29 July 1848 | Moderate | The Duke of Valencia | ||
| Pedro José Pidal The Marquis of Pidal | 29 July 1848 | 19 October 1849 | Moderate | The Duke of Valencia | ||
| Salvador de Cea Bermúdez The Count of Colombi | 19 October 1849 | 20 October 1849 | Moderate | The Count of Clonard | ||
| Pedro José Pidal The Marquis of Pidal | 20 October 1849 | 14 January 1851 | Moderate | The Duke of Valencia | ||
| Manuel Bertrán de Lis y Ribes | 14 January 1851 | 5 April 1851 | Moderate | Juan Bravo Murillo | ||
| Manuel de Pando The Marquis of Miraflores | 23 May 1851 | 7 August 1852 | Moderate | Juan Bravo Murillo | ||
| Manuel Bertrán de Lis y Ribes | 7 August 1852 | 14 December 1852 | Moderate | Juan Bravo Murillo | ||
| Federico de Roncali The Count of Alcoy | 14 December 1852 | 14 April 1853 | Moderate | The Count of Alcoy | ||
| Luis López de la Torre Ayllón y Kirsmacker | 14 April 1853 | 21 June 1853 | Moderate | Francisco de Lersundi y Hormaechea | ||
| Ángel Calderón de la Barca y Belgrano | 21 June 1853 | 17 July 1854 | Moderate | Francisco de Lersundi y Hormaechea | ||
| Ángel Calderón de la Barca y Belgrano | 21 June 1853 | 17 July 1854 | Moderate | The Count of San Luis | ||
| Luis Mayans y Enríquez de Navarra | 18 July 1854 | 19 July 1854 | Moderate | The Duke of Rivas | ||
| Joaquín Francisco Pacheco y Gutiérrez-Calderón | 30 July 1854 | 29 November 1854 | Moderate | The Duke of la Victoria | ||
| Claudio Antón de Luzuriaga | 29 November 1854 | 6 June 1855 | Progressive | The Duke of la Victoria | ||
| Juan de Zavala The Marquis of Sierra Bullones | 6 June 1855 | 14 July 1856 | Progressive | The Duke of la Victoria | ||
| Nicomedes Pastor Díaz y Corbelle | 14 July 1856 | 12 October 1856 | Liberal Union | The Count of Lucena | ||
| Pedro José Pidal The Marquis of Pidal | 12 October 1856 | 15 October 1857 | Moderate | The Duke of Valencia | ||
| Leopoldo Augusto de Cueto y López de Ortega Marquis of Valmar from 1877 | 15 October 1857 | 25 October 1857 | Moderate | Francisco Armero y Peñaranda | ||
| Francisco de Paula Martínez de la Rosa y Berdejo | 25 October 1857 | 14 January 1858 | Moderate | Francisco Armero y Peñaranda | - | |
| Francisco Javier de Istúriz y Montero | 14 January 1858 | 30 June 1858 | Moderate | Francisco Javier de Istúriz y Montero | - | |
| Leopoldo O'Donnell The Count of Lucena Duke of Tetuan from 1860 Acting | 30 June 1858 | 2 July 1858 | Liberal Union | The Duke of Tetuan | - | |
| Saturnino Calderón de la Barca y Collantes | 2 July 1858 | 17 January 1863 | Liberal Union | The Duke of Tetuan | - | |
| Francisco Serrano The Duke of la Torre | 17 January 1863 | 2 March 1863 | Liberal Union | The Duke of Tetuan | - | |
| Manuel de Pando The Marquis of Miraflores | 2 March 1863 | 17 January 1864 | Moderate | The Marquis of Miraflores | - | |
| Lorenzo Arrazola y García | 17 January 1864 | 1 March 1864 | Moderate | Lorenzo Arrazola y García | - | |
| Joaquín Francisco Pacheco y Gutiérrez-Calderón | 1 March 1864 | 16 September 1864 | Liberal Union | Alejandro Mon y Menéndez | ||
| Alejandro Llorente y Lannas | 16 September 1864 | 10 December 1864 | Moderate | The Duke of Valencia | ||
| Antonio de Benavides y Fernández de Navarrete | 10 December 1864 | 8 June 1865 | Moderate | The Duke of Valencia | - | |
| Lorenzo Arrazola y García Acting | 8 June 1865 | 21 June 1865 | Moderate | The Duke of Valencia | - | |
| Manuel Bermúdez de Castro y Díez | 21 June 1865 | 10 July 1866 | Liberal Union | The Duke of Tetuan | - | |
| Lorenzo Arrazola y García Acting | 10 July 1866 | 13 July 1866 | Moderate | The Duke of Valencia | - | |
| Eusebio Calonge y Fenollet | 13 July 1866 | 9 June 1867 | Moderate | The Duke of Valencia | - | |
| Alejandro de Castro y Casal | 9 June 1867 | 27 June 1867 | Moderate | The Duke of Valencia | - | |
| Lorenzo Arrazola y García | 27 June 1867 | 23 April 1868 | Moderate | The Duke of Valencia | - | |
| Joaquín de Roncali The Marquis of Roncali | 15 June 1868 | 20 September 1868 | Moderate | Luis González-Bravo y López de Arjona | - | |
| Joaquín de Roncali The Marquis of Roncali | 15 June 1868 | 20 September 1868 | Moderate | The Marquis of Havana | - | |
| Juan Álvarez de Lorenzana y Guerrero Viscount of Barrantes from 1870 | 8 October 1868 | 18 June 1869 | Liberal Union | The Duke of la Torre | ||
| Manuel Silvela y Le Vielleuze | 18 June 1869 | 1 November 1869 | Liberal Union | The Marquis of los Castillejos | ||
| Cristino Martos y Balbí | 1 November 1869 | 9 January 1870 | Democrat | The Marquis of los Castillejos | ||
| Práxedes Mateo-Sagasta y Escolar | 9 January 1870 | 25 December 1870 | Progressive | The Marquis of los Castillejos | ||
| Juan Bautista Topete y Carballo | 27 December 1870 | 4 January 1871 | Liberal Union | Juan Bautista Topete y Carballo | ||
| Cristino Martos y Balbí | 4 January 1871 | 24 July 1871 | Radical | The Duke of la Torre | ||
| Fernándo Fernández de Córdova The Marquis of Mendigorría Acting | 24 July 1871 | 5 October 1871 | Radical | Manuel Ruiz Zorrilla | ||
| José Malcampo The Marquis of San Rafael Acting | 5 October 1871 | 20 November 1871 | Constitutional | The Marquis of San Rafael | ||
| Bonifacio de Blas y Muñoz | 20 November 1871 | 26 May 1872 | Constitutional | The Marquis of San Rafael | ||
| Bonifacio de Blas y Muñoz | 20 November 1871 | 26 May 1872 | Constitutional | Práxedes Mateo-Sagasta y Escolar | ||
| Augusto Ulloa y Castañón | 26 May 1872 | 13 June 1872 | Constitutional | The Duke of la Torre | ||
| Cristino Martos y Balbí | 13 June 1872 | 11 February 1873 | Radical | Manuel Ruiz Zorrilla |
First Spanish Republic (1873–74)
Ministers of State
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Prime Minister | Refs |
| Emilio Castelar y Ripoll | 11 February 1873 | 11 June 1873 | Republican | Estanislao Figueras y Moragas | ||
| José Muro y López-Salgado | 11 June 1873 | 28 June 1873 | Republican | Francisco Pi y Margall | ||
| Eleuterio Maisonnave y Cutayar | 28 June 1873 | 18 July 1873 | Republican | Francisco Pi y Margall | ||
| Santiago Soler y Pla | 18 July 1873 | 7 September 1873 | Republican | Nicolás Salmerón y Alonso | ||
| José de Carvajal y Hué | 7 September 1873 | 3 January 1874 | Republican | Emilio Castelar y Ripoll | ||
| Práxedes Mateo-Sagasta y Escolar | 3 January 1874 | 13 May 1874 | Constitutional | The Duke of la Torre | ||
| Práxedes Mateo-Sagasta y Escolar | 3 January 1874 | 13 May 1874 | Constitutional | The Marquis of Sierra Bullones | ||
| Augusto Ulloa y Castañón | 13 May 1874 | 31 December 1874 | Constitutional | The Marquis of Sierra Bullones | ||
| Augusto Ulloa y Castañón | 13 May 1874 | 31 December 1874 | Constitutional | Práxedes Mateo-Sagasta y Escolar |
Kingdom of Spain (1874–1931)
Ministers of State (1874–1928)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Prime Minister | Refs |
| Alejandro de Castro y Casal | 31 December 1874 | 12 September 1875 | Conservative | Antonio Cánovas del Castillo | - | |
| Emilio Alcalá-Galiano The Count of Casa Valencia | 12 September 1875 | 29 November 1875 | Conservative | Joaquín Jovellar y Soler | - | |
| Fernando Calderón de la Barca y Collantes Marquis of Reinosa from 1878 | 2 December 1875 | 14 January 1877 | Conservative | Antonio Cánovas del Castillo | - | |
| Manuel Silvela y Le Vielleuze | 14 January 1877 | 7 March 1879 | Conservative | Antonio Cánovas del Castillo | - | |
| Francisco de Borja Queipo de Llano The Count of Toreno Acting | 7 March 1879 | 10 March 1879 | Conservative | Antonio Cánovas del Castillo | - | |
| Mariano Roca de Togores The Marquis of Molíns | 10 March 1879 | 16 May 1879 | Conservative | Arsenio Martínez-Campos y Antón | - | |
| Carlos O'Donnell The Duke of Tetuan | 16 May 1879 | 9 December 1879 | Conservative | Arsenio Martínez-Campos y Antón | - | |
| Francisco de Borja Queipo de Llano The Count of Toreno | 9 December 1879 | 20 January 1880 | Conservative | Antonio Cánovas del Castillo | - | |
| Antonio Cánovas del Castillo Acting | 20 January 1880 | 19 March 1880 | Conservative | Antonio Cánovas del Castillo | - | |
| José de Elduayen The Marquis of the Pazo de la Merced | 19 March 1880 | 8 February 1881 | Conservative | Antonio Cánovas del Castillo | - | |
| Antonio González de Aguilar The Marquis of la Vega de Armijo | 8 February 1881 | 13 October 1883 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Servando Ruiz-Gómez y González-Llanos | 13 October 1883 | 18 January 1884 | Liberal | José de Posada y Herrera | - | |
| José de Elduayen The Marquis of the Pazo de la Merced | 18 January 1884 | 27 November 1885 | Conservative | Antonio Cánovas del Castillo | - | |
| Segismundo Moret y Prendergast | 27 November 1885 | 14 June 1888 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Antonio González de Aguilar The Marquis of la Vega de Armijo | 14 June 1888 | 5 July 1890 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Carlos O'Donnell The Duke of Tetuan | 5 July 1890 | 11 December 1892 | Conservative | Antonio Cánovas del Castillo | - | |
| Antonio González de Aguilar The Marquis of la Vega de Armijo | 11 December 1892 | 5 April 1893 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Segismundo Moret y Prendergast | 12 March 1894 | 4 November 1894 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Alejandro Groizard y Gómez de la Serna | 4 November 1894 | 23 March 1895 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Carlos O'Donnell The Duke of Tetuan | 23 March 1895 | 19 January 1896 | Conservative | Antonio Cánovas del Castillo | - | |
| José de Elduayen The Marquis of the Pazo de la Merced | 19 January 1896 | 5 March 1896 | Conservative | Antonio Cánovas del Castillo | - | |
| Carlos O'Donnell The Duke of Tetuan | 5 March 1896 | 4 October 1897 | Conservative | Antonio Cánovas del Castillo | - | |
| Carlos O'Donnell The Duke of Tetuan | 5 March 1896 | 4 October 1897 | Conservative | Marcelo de Azcárraga y Palmero | - | |
| Pío Gullón e Iglesias | 4 October 1897 | 18 May 1898 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| José Gutiérrez de Agüera Acting | 18 May 1898 | 24 May 1898 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Juan Manuel Sánchez The Duke of Almodóvar del Río | 24 May 1898 | 4 March 1899 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Francisco Silvela y Le Vielleuze | 4 March 1899 | 18 April 1900 | Conservative | Francisco Silvela y Le Vielleuze | - | |
| Ventura García-Sancho The Marquis of Aguilar de Campoo | 18 April 1900 | 6 March 1901 | Conservative | Francisco Silvela y Le Vielleuze | - | |
| Ventura García-Sancho The Marquis of Aguilar de Campoo | 18 April 1900 | 6 March 1901 | Conservative | Marcelo de Azcárraga y Palmero | - | |
| Juan Manuel Sánchez The Duke of Almodóvar del Río | 6 March 1901 | 6 December 1902 | Liberal | Práxedes Mateo-Sagasta y Escolar | - | |
| Buenaventura de Abarzuza y Ferrer | 6 December 1902 | 20 July 1903 | Conservative | Francisco Silvela y Le Vielleuze | - | |
| Manuel de Mariátegui The Count of San Bernardo | 20 July 1903 | 5 December 1903 | Conservative | The Marquis of Pozo Rubio | - | |
| Faustino Rodríguez-San Pedro y Díaz-Argüelles | 5 December 1903 | 16 December 1904 | Conservative | Antonio Maura y Montaner | - | |
| Ventura García-Sancho The Marquis of Aguilar de Campoo | 16 December 1904 | 27 January 1905 | Conservative | Marcelo de Azcárraga y Palmero | - | |
| Wenceslao Ramírez de Villa-Urrutia Marquis of Villa-Urrutia from 1916 | 27 January 1905 | 23 June 1905 | Conservative | The Marquis of Pozo Rubio | - | |
| Felipe Sánchez Román | 23 June 1905 | 31 October 1905 | Liberal | Eugenio Montero Ríos | - | |
| Pío Gullón e Iglesias | 31 October 1905 | 1 December 1905 | Liberal | Eugenio Montero Ríos | - | |
| Juan Manuel Sánchez The Duke of Almodóvar del Río | 1 December 1905 | 23 June 1906 | Liberal | Segismundo Moret y Prendergast | - | |
| Emilio de Ojeda y Perpiñán Acting | 23 June 1906 | 1 July 1905 | Liberal | Segismundo Moret y Prendergast | - | |
| Juan Pérez-Caballero y Ferrer | 1 July 1906 | 6 July 1906 | Liberal | Segismundo Moret y Prendergast | - | |
| Pío Gullón e Iglesias | 6 July 1906 | 30 November 1906 | Liberal | José López Domínguez | - | |
| Juan Pérez-Caballero y Ferrer | 30 November 1906 | 25 January 1907 | Liberal | Segismundo Moret y Prendergast | - | |
| Juan Pérez-Caballero y Ferrer | 30 November 1906 | 25 January 1907 | Liberal | The Marquis of la Vega de Armijo | - | |
| Manuel Allendesalazar y Muñoz de Salazar | 25 January 1907 | 21 October 1909 | Conservative | Antonio Maura y Montaner | - | |
| Juan Pérez-Caballero y Ferrer | 21 October 1909 | 9 February 1910 | Liberal | Segismundo Moret y Prendergast | - | |
| Manuel García-Prieto The Marquis of Alhucemas | 9 February 1910 | 31 December 1912 | Liberal | José Canalejas y Méndez | - | |
| Manuel García-Prieto The Marquis of Alhucemas | 9 February 1910 | 31 December 1912 | Liberal | The Count of Romanones | - | |
| Juan Navarro-Reverter y Gomis | 31 December 1912 | 13 June 1913 | Liberal | The Count of Romanones | - | |
| Antonio López Muñoz Count of López Muñoz from 1920 | 13 June 1913 | 27 October 1913 | Liberal | The Count of Romanones | - | |
| Salvador Bermúdez de Castro The Duke of Ripalda | 27 October 1913 | 9 December 1915 | Conservative | Eduardo Dato e Iradier | - | |
| Miguel Villanueva y Gómez | 9 December 1915 | 25 February 1916 | Liberal | The Count of Romanones | - | |
| Álvaro de Figueroa The Count of Romanones Acting | 25 February 1916 | 30 April 1916 | Liberal | The Count of Romanones | - | |
| Amalio Gimeno The Count of Gimeno | 30 April 1916 | 19 April 1917 | Liberal | The Count of Romanones | - | |
| Juan Alvarado y del Saz | 19 April 1917 | 11 June 1917 | Liberal | The Marquis of Alhucemas | - | |
| Salvador Bermúdez de Castro The Duke of Ripalda | 11 June 1917 | 13 November 1917 | Conservative | Eduardo Dato e Iradier | - | |
| Manuel García-Prieto The Marquis of Alhucemas | 13 November 1917 | 22 March 1918 | Liberal | The Marquis of Alhucemas | - | |
| Eduardo Dato e Iradier | 22 March 1918 | 9 November 1918 | Conservative | Antonio Maura y Montaner | - | |
| Álvaro de Figueroa The Count of Romanones | 9 November 1918 | 15 April 1919 | Liberal | The Marquis of Alhucemas | - | |
| Álvaro de Figueroa The Count of Romanones | 9 November 1918 | 15 April 1919 | Liberal | The Count of Romanones | - | |
| Manuel González-Hontoria y Fernández-Ladreda | 15 April 1919 | 20 July 1920 | Conservative | Antonio Maura y Montaner | - | |
| Salvador Bermúdez de Castro The Duke of Ripalda | 20 July 1920 | 14 August 1921 | Conservative | Joaquín Sánchez de Toca y Calvo | - | |
| Salvador Bermúdez de Castro The Duke of Ripalda | 20 July 1920 | 14 August 1921 | Conservative | Manuel Allendesalazar y Muñoz de Salazar | - | |
| Salvador Bermúdez de Castro The Duke of Ripalda | 20 July 1920 | 14 August 1921 | Conservative | Eduardo Dato e Iradier | - | |
| Salvador Bermúdez de Castro The Duke of Ripalda | 20 July 1920 | 14 August 1921 | Conservative | Manuel Allendesalazar y Muñoz de Salazar | - | |
| Manuel González-Hontoria y Fernández-Ladreda | 14 August 1921 | 8 March 1922 | Conservative | Antonio Maura y Montaner | - | |
| Joaquín Fernández Prida | 8 March 1922 | 4 December 1922 | Conservative | José Sánchez-Guerra y Martínez | - | |
| Francisco Bergamín y García | 4 December 1922 | 7 December 1922 | Conservative | José Sánchez-Guerra y Martínez | - | |
| Santiago Alba y Bonifaz | 7 December 1922 | 15 September 1923 | Liberal | The Marquis of Alhucemas | - | |
| Fernando Espinosa de los Monteros y Bermejillo | 15 September 1923 | 3 December 1925 | - | The Marquis of Estella | - | |
| José de Yanguas y Messía Viscount of Santa Clara de Avedillo from 1929 | 3 December 1925 | 20 February 1927 | - | The Marquis of Estella | - | |
| Miguel Primo de Rivera The Marquis of Estella | 20 February 1927 | 3 November 1928 | - | The Marquis of Estella | - |
President and Minister of Foreign Affairs (1928–30)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Prime Minister | Refs |
| Miguel Primo de Rivera The Marquis of Estella | 3 November 1928 | 30 January 1930 | - | The Marquis of Estella |
Ministers of State (1930–31)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Prime Minister | Refs |
| Jacobo Fitz-James Stuart The Duke of Alba | 30 January 1930 | 18 February 1931 | - | The Marquis of Estella | ||
| Álvaro de Figueroa The Count of Romanones | 30 January 1930 | 18 February 1931 | - | The Count of Xauen | ||
| Álvaro de Figueroa The Count of Romanones | 30 January 1930 | 18 February 1931 | - | Juan Bautista Aznar-Cabañas |
Second Spanish Republic (1931–39)
Ministers of State
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Prime Minister | Refs |
| Alejandro Lerroux y García | 14 April 1931 | 16 December 1931 | Radical | Niceto Alcalá-Zamora y Torres | - | |
| Alejandro Lerroux y García | 14 April 1931 | 16 December 1931 | Radical | Manuel Azaña y Díaz | - | |
| Luis de Zulueta y Escolano | 16 December 1931 | 12 June 1933 | Republican Action | Manuel Azaña y Díaz | - | |
| Fernando de los Ríos y Urruti | 12 June 1933 | 12 September 1933 | PSOE | Manuel Azaña y Díaz | - | |
| Claudio Sánchez-Albornoz y Menduiña | 12 September 1933 | 16 December 1933 | Republican Action | Alejandro Lerroux y García | - | |
| Claudio Sánchez-Albornoz y Menduiña | 12 September 1933 | 16 December 1933 | Republican Action | Diego Martínez Barrio | - | |
| Leandro Pita Romero | 16 December 1933 | 4 October 1934 | ORGA | Alejandro Lerroux y García | - | |
| Leandro Pita Romero | 16 December 1933 | 4 October 1934 | ORGA | Ricardo Samper | - | |
| Ricardo Samper | 4 October 1934 | 16 November 1934 | Radical | Alejandro Lerroux y García | - | |
| Juan José Rocha García | 16 November 1934 | 25 September 1935 | Radical | Alejandro Lerroux y García | - | |
| Alejandro Lerroux y García | 25 September 1935 | 29 October 1935 | Radical | Joaquín Chapaprieta | - | |
| José Martínez de Velasco | 29 October 1935 | 30 December 1935 | Agrarian | Joaquín Chapaprieta | - | |
| José Martínez de Velasco | 29 October 1935 | 30 December 1935 | Agrarian | Manuel Portela | - | |
| Joaquín Urzaiz Cadaval | 30 December 1935 | 19 February 1936 | Liberal Republican Right | Manuel Portela | - | |
| Augusto Barcía Trelles | 19 February 1936 | 19 July 1936 | Republican Left | Manuel Azaña | - | |
| Augusto Barcía Trelles | 19 February 1936 | 19 July 1936 | Republican Left | Augusto Barcía Trelles | - | |
| Augusto Barcía Trelles | 19 February 1936 | 19 July 1936 | Republican Left | Santiago Casares Quiroga | - | |
| Justino de Azcárate | 19 July 1936 | 19 July 1936 | National Republican Party | Diego Martínez Barrio | - | |
| Augusto Barcía Trelles | 19 July 1936 | 4 September 1936 | Republican Left | José Giral | - | |
| Julio Álvarez del Vayo | 4 September 1936 | 17 May 1937 | PSOE | Francisco Largo Caballero | - | |
| José Giral | 17 May 1937 | 5 April 1938 | Republican Left | Juan Negrín | - | |
| Julio Álvarez del Vayo | 5 April 1938 | 31 March 1939 | PSOE | Juan Negrín | - |
Francoist Spain (1939–75)
Ministers of Foreign Affairs
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | Head of State | Refs |
| Francisco Gómez-Jordana Sousa The Count of Jordana | 31 January 1938 | 9 August 1939 | - | Francisco Franco y Bahamonde | ||
| Juan Luis Beigbeder y Atienza | 9 August 1939 | 16 October 1940 | Falangist | Francisco Franco y Bahamonde | ||
| Ramón Serrano Suñer | 16 October 1940 | 3 September 1942 | Falangist | Francisco Franco y Bahamonde | ||
| Francisco Gómez-Jordana Sousa The Count of Jordana | 3 September 1942 | 3 August 1944 | - | Francisco Franco y Bahamonde | ||
| José Félix de Lequerica y Erquiza | 11 August 1944 | 20 July 1945 | Falangist | Francisco Franco y Bahamonde | ||
| Alberto Martín-Artajo y Álvarez | 20 July 1945 | 25 February 1957 | - | Francisco Franco y Bahamonde | ||
| Fernando María Castiella y Maíz | 25 February 1957 | 29 October 1969 | Falangist | Francisco Franco y Bahamonde | ||
| Gregorio López-Bravo y Castro | 29 October 1969 | 11 June 1973 | - | Francisco Franco y Bahamonde | - | |
| Laureano López Rodó | 11 June 1973 | 3 January 1974 | - | Luis Carrero Blanco | - | |
| Pedro Cortina Mauri | 3 January 1974 | 11 December 1975 | - | Carlos Arias Navarro | - |
Kingdom of Spain (since 1975)
Ministers of Foreign Affairs (1975–2004)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | President of the Government |
| José María de Areilza The Count of Motrico | 11 December 1975 | 7 July 1976 | Democratic Coalition | Carlos Arias Navarro | |
| Marcelino Oreja y Aguirre Marquis of Oreja from 2010 | 7 July 1976 | 8 September 1980 | Union of the Democratic Centre | Adolfo Suárez González | |
| José Pedro Pérez-Llorca | 8 September 1980 | 2 December 1982 | Union of the Democratic Centre | Adolfo Suárez González | |
| José Pedro Pérez-Llorca | 8 September 1980 | 2 December 1982 | Union of the Democratic Centre | Leopoldo Calvo-Sotelo y Bustelo | |
| Fernando Morán | 2 December 1982 | 4 July 1985 | Socialist | Felipe González Márquez | |
| Francisco Fernández Ordóñez | 4 July 1985 | 24 June 1992 | Socialist | Felipe González Márquez | |
| Javier Solana y Madariaga | 24 June 1992 | 18 December 1995 | Socialist | Felipe González Márquez | |
| Carlos Westendorp y Cabeza | 18 December 1995 | 5 May 1996 | Socialist | Felipe González Márquez | |
| Abel Matutes y Juan | 5 May 1996 | 27 April 2000 | People's Party | José María Aznar López | |
| Josep Piqué | 27 April 2000 | 9 July 2002 | People's Party | José María Aznar López | |
| Ana de Palacio y del Valle-Lersundi | 9 July 2002 | 17 April 2004 | People's Party | José María Aznar López |
Ministers of Foreign Affairs and Cooperation (2004–2018)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | President of the Government | Refs |
| Miguel Ángel Moratinos Cuyaubé | 18 April 2004 | 20 October 2010 | Socialist | José Luis Rodríguez Zapatero | ||
| Trinidad Jiménez García-Herrera | 20 October 2010 | 22 December 2011 | Socialist | José Luis Rodríguez Zapatero | ||
| José García-Margallo y Marfil | 22 December 2011 | 4 November 2016 Acting | People's Party | Mariano Rajoy Brey | ||
| Alfonso Dastis Quecedo | 4 November 2016 | 1 June 2018 | Independent | Mariano Rajoy Brey |
Ministers of Foreign Affairs, European Union and Cooperation (since 2018)
Political Persuasion:| Portrait | Name | Entered office | Left office | Political party | President of the Government |
| Josep Borrell | 7 June 2018 | 30 November 2019 | Spanish Socialist Workers' Party | Pedro Sánchez | |
| Margarita Robles | 30 November 2019 | 13 January 2020 | Spanish Socialist Workers' Party | Pedro Sánchez | |
| Arancha González Laya | 13 January 2020 | Incumbent | Independent | Pedro Sánchez |