At the 2000 Summer Olympics she won a gold medal in the hammer throw, with a new personal best throw of 71.16 metres. Gold medal favourite Mihaela Melinte was disqualified shortly before the start of the qualifying round for failing a drugs test. At age 17 years and 331 days, Skolimowska became the youngest Olympic hammer champion. As it was the first time that the women's hammer throw was staged at the Olympics, she also set an Olympic record, which stood for four years. She received the Polish Golden Cross of Merit for her achievement.
Career after the Olympic gold
In the 2001 season, she finished fourth at the 2001 World Championships in Edmonton, with a throw of 68.05 metres. One month later she improved her national record to 71.71 metres, which was enough to win the IAAF Grand Prix Final in Melbourne. In 2002, she took her first championships medal since the Olympic victory, at the 2002 European Championships. Throwing 72.46 metres to take the silver medal behind Olga Kuzenkova, she almost improved on her 72.60 result achieved in June in Bydgoszcz. Toward the end of the season she finished fifth at the 2002 World Cup. Skolimowska did not set new national records in 2003 and 2004. In 2003, she finished eighth both at the 2003 World Championships and the 2003 World Athletics Final. In the final round of the hammer throw at the 2004 Summer Olympics in Athens she recorded a season best of 72.57 metres, placing fifth overall in the event. She again finished fifth at the 2004 World Athletics Final.
New records
In July 2005 Skolimowska improved her national record to 74.27 metres, the result being achieved in Madrid. Exactly one month later she won the gold medal at the Universiade, four days after finishing seventh at the 2005 World Championships. At the 2005 World Athletics Final she finished second. In 2006 Skolimowska improved her national record again; to 75.29 as she won the 2006 World Cup meet in September in Athens. The record crowned a successful year, with a bronze medal at the 2006 European Championships and a second place at the 2006 World Athletics Final earlier in the season. In 2007 Skolimowska improved with more than a metre, throwing 76.83 in May at the Super Grand Prix meet in Doha. She finished fourth at both the 2007 World Championships and the 2007 World Athletics Final. 2008, however, was an unsuccessful year. Her season's best was only 73.50, achieved in June in Warsaw. In the Olympic competition, she did progress from the qualifying round, but failed to register a valid mark in the final, thus finishing unplaced.
Death
Skolimowska died unexpectedly at the age of 26 during a training session in Portugal. The cause of her death was confirmed by autopsy to be pulmonary embolism.