Isocetane
Isocetane is a highly branched alkane used as a reference in determining the cetane number of diesel. It is given a cetane number of 15. Isocetane replaced 1-methylnaphthalene as the lower reference for cetane number owing to the expense of 1-methylnaphthalene, and difficulty in safe handling.
Strictly speaking, if the standard meaning of ‘iso’ is followed, the name isocetane should be reserved for the isomer 2-Methylpentadecane. However, 2,2,4,4,6,8,8-heptamethylnonane is by far the most important isomer of cetane and so, historically, it has ended up with this name.
