Promoted to post-captain on 15 January 1747, Hervey was given command of the third-rate HMS Princess at that time and of the sixth-rate HMS Phoenix in January 1752 and saw action in her at the Battle of Minorca in May 1756. He went on to command the fourth-rate HMS Defiance later that month, the third-rate HMS Hampton Court in May 1757 and the third-rate HMS Monmouth in March 1758. Hervey distinguished himself in several encounters with the French, and was of great assistance to Admiral Hawke in 1759, although he had returned to England before the Battle of Quiberon Bay in November 1759. He took command of the third-rate HMS Dragon in March 1760 and saw action during the Capture of Belle Île in June 1761, the Invasion of Martinique in January 1762 and the Battle of Havana in June 1762 before transferring to the fourth-rate HMS Centurion in May 1763. Having served with distinction in the West Indies under Rodney, his active life at sea ceased when the Peace of Paris was concluded in February 1763. He was, however, nominally Commander-in-Chief of the Mediterranean Fleet in this year. He was promoted to rear-admiral on 31 March 1775 and to vice-admiral on 23 January 1778. He was known as the English Casanova, due to his colourful personal life.
In August 1744 Hervey had been secretly married to Elizabeth Chudleigh, afterwards Duchess of Kingston, but this union was dissolved in 1769. Lord Bristol died leaving no legitimate issue, and having, as far as possible, alienated his property from the title. In about 1765 Hervey paid to take Ann Elliot off the stage to become his mistress. She would go on to take the King's brother as her lover. From 1775 Hervey had taken as his mistress Mary Nesbitt, a former artists' model of some notoriety. They lived together, apparently faithfully, at his Surrey home of Norwood House and she received property in his will. He made changes to Norwood House including an ornamental lake and a stable. He died due to a gout in the stomach at St James's Square, London on 23 December 1779, aged 55, and was buried at Ickworth in Suffolk; he was succeeded by his brother Frederick. Many of his letters are in the Record Office, and his journals in the British Museum. Other letters are printed in the Grenville Papers, vols. iii. and iv., and the Life of Admiral Keppel, by the Rev. Thomas Keppel. Hervey Bay, Queensland, a bay and city in Australia, was named after him by Captain James Cook while carrying out the survey of the east coast of Australia on 22 May 1770. Bristol Bay, the rich salmon fishing ground in southwest Alaska, was so named in honor of Hervey by Captain James Cook, who first charted the region in July 1778. Bristol Island, a five mile long ice-covered quake-prone chain of volcanos in the South Sandwich Islands and the coral atoll comprising the islands of Manuae and Te-O-Au-Tu in the Cook Islands were also named in honour of Hervey by Captain James Cook.